Considering I haven't seen any hero with a base stat total lower than 50, I'd want a SS of that.
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To answer your questions the highest base stat of a hero is 89 (Mars heroes), when calculated as Stat-Level=BaseStat. That is without boosters such as excalibur.
There is a whole thread already debating wether it should be 89 or 90, but I won't go into that here. It is only a mathematical definition.
From what I have seen 89 is the max. heard rumors of bases in the 90s but never seen one. heres a 88 and 89.
http://img691.imageshack.us/img691/8403/laurak.jpg
http://img580.imageshack.us/img580/8159/miranday.jpg
I prefer to calculate base at lvl 0
here's my 89 base(at lvl 0) and/or 90 base(at lvl 1), depends on how the viewer calculates it...
http://img139.imageshack.us/img139/9856/ambika.jpg
Dont ask me why i put excal on my 3rd best hero ;) :p
Btw, my prized possesion, my first hero:
http://img52.imageshack.us/img52/1931/ahalya.jpg
62 Base :( She was rly tough to lvl up... Now i've stopped, and focusing on my 89 base now... :D
Take Care... :)